Six novel Zr(IV)- and Hf(IV)-based MOFs, namely DUT-67, DUT-68, and DUT-69 (DUT, Dresden University of Technology) were obtained using a modulated synthesis approach with the acetic acid as a modula
Two structurally different polymorphs of cobalt(II) imidazolate frameworks are solvothermally synthesized by using N,N-dimethylacetamide as a template: The polymorph 6 (a = 9.797 (4) Å, b = 15.301(6)
RPF-4 is a family of polymeric frameworks prepared with rare-earth elements and the versatile ligand 4,4′-(hexafluoroisopropylidene)bis(benzoic acid). We have found that during the synthesis procedure
We present an in situ powder X-ray diffraction study on the phase stability and polymorphism of the metal–organic framework ZIF-4, Zn(imidazolate)2, at simultaneous high pressure and high temperature
An organometallic sandwich compound of terephthalic acid, namely, [(η5-Cp)FeII{η6-(1,4-C6H4(COOH)2)}]+ (H21+), is reported, along with X-ray single crystal structures of [H1·H21][PF6] and H1. [H21·H1]
