Pt(PEt<sub>3</sub>)(κ<sup>2</sup>-P,C-PEt<sub>2</sub>CHMe)(C<sub>6</sub>Cl<sub>5</sub>): An Unexpected Intermediate in the Synthesis of <i>cis</i>-Pt(PEt<sub>3</sub>)<sub>2</sub>(Cl)(C<sub>6</sub>Cl<sub>5</sub>)
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Addition of 1 to 6 equiv of LiC6Cl5 to cis-Pt(PEt3)2Cl2 gives the unexpected phosphine ligand C−H bond activation product Pt(PEt3)(κ2-P,C-PEt2CHMe)(C6Cl5) (1). Aqueous HCl addition to 1 gives the previously reported product of the reaction, cis-Pt(PEt3)2(Cl)(C6Cl5) (2).
创建时间:
2011-03-28



