Reactivity Studies of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6‑iPr2C6H3) with 2‑Aminobenzenethiol, 2‑Aminophenol, and 1,4-Dithiane-2,5-diol
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https://figshare.com/articles/dataset/Reactivity_Studies_of_LAlH_sub_2_sub_L_HC_CMeNAr_sub_2_sub_Ar_2_6_i_i_i_Pr_sub_2_sub_C_sub_6_sub_H_sub_3_sub_with_2_Aminobenzenethiol_2_Aminophenol_and_1_4_Dithiane_2_5_diol/2488906
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The reaction of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with 2-aminobenzenethiol, 2-aminophenol, and 1,4-dithiane-2,5-diol resulted in the compounds LAl[(μ-N)(μ-S)](o-C6H4) (2), LAl[(μ-O)(o-C6H4)(NH2)]2 (3), and LAl(μ-O)2(p-dithiane) (4), respectively. Compound 2 features an organic–inorganic hybrid containing an NAlSC2 five-membered ring, while compound 3 exhibits a C–O–Al–O–C chain structure. Compound 4 forms a basket-like molecule with the C4S2 unit as the bottom part and O2Al as the handle. Complexes 2, 3, and 4 were characterized by 1H NMR, elemental analysis, and single-crystal X-ray diffraction studies.
创建时间：
2016-02-20
