NOAA/WDS Paleoclimatology - Keche Lake, Alaska 3500 Year Multiproxy Sediment Data

Analyses of oxygen and carbon isotopes in bulk carbonate and Chara-stem encrustations, X-ray diffraction, and sediment composition from Keche Lake offer new information on climatic change over the past ~3,400 years in northeastern interior Alaska. The d18O and dD values of water samples from the lake and its inlet streams suggest that evaporation plays an important role in determining the isotopic composition of Keche Lake water at present. However, evaporative enrichment does not appear to be a major driver of the pronounced fluctuations in the bulk-carbonate d18O record on the basis of comparison with Chara-d18O values. The d18O values of bulk carbonate in the Keche Lake sediments vary by up to 10 ‰ over the past 3,400 years, with maximum values of -12 ‰ around 3,400 cal BP and between 2,100 and 1,500 cal BP. High d18O peaks are associated with sediments dominated by quartz, feldspar, and clay minerals suggesting the influence of detrital carbonate. Multi-millennial patterns of d18O variation at Keche Lake appear to be linked with changes in watershed and sediment-depositional processes, which may be driven by varying moisture abundance associated with the position of the Aleutian Low (AL). The increasing trend of carbonate d18O from 3,400 to ~2,100 cal BP probably reflects the increasing importance of a westerly AL, and the high frequency of d18O spikes ~2,100–1,500 cal BP may have resulted from the prevalence of a westerly AL position. Predominance of a westerly AL likely increased snowfall and winter temperature in the region. Such conditions would have promoted soil erosion and thermokarst activity during spring snowmelt, resulting in episodic large influxes of detrital carbonate to Keche Lake and elevating bulk-carbonate d18O. Over the past 1,500 years, bulk-carbonate d18O remained relatively high at Keche Lake but variation was much less pronounced than before. A broad d18O peak centered ~400 cal BP may be related to enhanced winter moisture during the Little Ice Age, although our chronology is inadequate for a rigorous assessment of this interpretation. This study contributes a new d18O record and offers additional information on past moisture-regime shifts associated with changing atmospheric-circulation patterns.