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Regioselective [2 + 2 + 2] Cycloaddition of a Nickel−Benzyne Complex with 1,3-Diynes

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Regioselective_2_2_2_Cycloaddition_of_a_Nickel_Benzyne_Complex_with_1_3-Diynes/3747159
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资源简介:
Reactions of nickel(0)−benzyne complexes with a range of symmetrically substituted 1,3-diynes in the presence of triethylphosphine lead to the regioselective formation of 2,3-dialkynyl naphthalenes. The regioselectivity can be reversed when the diyne possesses substituents of high steric bulk, allowing selective formation of either symmetric dialkynyl naphthalene.
创建时间:
2016-08-20
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