<b>Absolute asymmetric synthesis of a homochiral polymer from an achiral monomer</b>

The present work discusses about the absolute asymmetric synthesis of homochiral polymer from achiral monomers via topochemical reactions.Mono fid folder has all the monomer nmr data corresponding to Supplementary Fig. 7 to Supplementary Fig. 11fid file 70 c folder has all the temperature-dependent nmr data at 70 C corresponding to Fig. 2a in manuscript100 c fid folder has all the temperature-dependent nmr data at 100 C corresponding to Fig. 2b in manuscriptIR text folder has all the temperature-dependent ir data at 70 C corresponding to Fig. 2c in manuscriptfid solid-state folder has all the solid-state data of monomer and polymer correspoonding to Fig.2d in the manuscriptPXRD mono only folder corresponds to fig. 3b in manuscriptPXRD kinetics text folder corresponds to fig. 3c in manuscriptfid 120 c folder corresponds to Supplementary Fig. 3 in SI63-fid folder corresponds to Supplementary Fig to 16-18Dx-67-poly gpc corresponds to Fig. 3a in manuscript