Cobalt-Catalyzed C–H Borylation
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https://figshare.com/articles/dataset/Cobalt_Catalyzed_C_H_Borylation/2030193
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资源简介：
A family of pincer-ligated cobalt
complexes has been synthesized
and are active for the catalytic C−H borylation of heterocycles
and arenes. The cobalt catalysts operate with high activity and under
mild conditions and do not require excess borane reagents. Up to 5000
turnovers for methyl furan-2-carboxylate have been observed at ambient
temperature with 0.02 mol % catalyst loadings. A catalytic cycle that
relies on a cobalt(I)–(III) redox couple is proposed.
创建时间：
2015-12-17
