11-Step Total Synthesis of Pallambins C and D
收藏NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/11-Step_Total_Synthesis_of_Pallambins_C_and_D/3427076
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资源简介：
The
structurally intriguing terpenes pallambins C and D have been
assembled in only 11 steps from a cheap commodity chemical: furfuryl
alcohol. This synthesis, which features a redox-economic approach
free of protecting-group manipulations, assembles all four-ring systems
via a sequential cyclization strategy. Of these four-ring constructing
operations, two are classical (Robinson annulation and Mukaiyama aldol)
and two are newly devised. During the course of this work a method
for the difunctionalization of enol ethers was developed, and the
scope of this transformation was explored.
创建时间：
2016-06-17
