Synthesis of Tungsten and Molybdenum Carbon Dioxide Complexes
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https://figshare.com/articles/dataset/Synthesis_of_Tungsten_and_Molybdenum_Carbon_Dioxide_Complexes/2416033
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资源简介：
Tungsten and molybdenum η2-CO2 complexes
of the form TpM(NO)(L)(η2-CO2), where
M = W, Mo, Tp = tris(pyrazolyl)borate, and L = PMe3, 1-methylimidazole,
have been synthesized by displacement of an η2-aromatic
ligand under elevated CO2 pressure. These complexes have
been characterized by single-crystal X-ray diffraction. The η2-CO2 complexes are air stable and resist decomposition
in solution. In addition, the molybdenum η2-CO2 complex undergoes chemical reduction of the η2-CO2 ligand to form TpMo(NO)(1-methylimidazole)(CO).
创建时间：
2013-05-13
