Chemoselectivity and Enantioselectivity in the Conjugate Reduction of Cinnamate esters and a Tandem Conjugate-Reduction-Ester Hydrogenation using Manganese Catalysts (dataset)
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https://research-portal.st-andrews.ac.uk/en/datasets/715cb8e1-d12f-4163-8702-82873da3dac5
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资源简介：
The dataset contains the NMR data for the catalysis products obtained after reduction with a Mn complex. Chemoselective hydrogenation of the C=C bonds of t-butyl cinnamate esters can be realised using Mn/phosphino-ferrocenyl-amino-methyl-pyridine catalysts. Moderately enantioselective conjugate reduction of a trisubstituted cinnamate ester is possible. Alternatively, tandem conjugate reduction-ester hydrogenation with very high sequence selectivity (<1% allylic alcohol by-product) can be realised.
提供机构：
University of St Andrews
创建时间：
2026-01-12
