A New Type of Phosphaferrocene–Pyrrole–Phosphaferrocene P-N-P Pincer Ligand
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https://figshare.com/articles/dataset/A_New_Type_of_Phosphaferrocene_Pyrrole_Phosphaferrocene_P_N_P_Pincer_Ligand/2537512
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资源简介：
A 2-ethoxycarbonylphosphaferrocene was reduced to the
corresponding 2-hydroxymethyl derivative, which was condensed with
pyrrole in a 2:1 ratio in the presence of BF3 to give a
phosphaferrocene–pyrrole–phosphaferrocene pincer ligand.
This tridentate ligand, in turn, reacted with [Rh(acac)(CO)2] to yield a rhodium carbonyl pincer complex. This complex was characterized
by X-ray crystal structure analysis and tested in the hydroformylation
of internal olefins.
创建时间：
2016-02-21
