Synthesis of an N‑Heterocyclic-Carbene-Stabilized Siladiimide
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https://figshare.com/articles/dataset/Synthesis_of_an_N_Heterocyclic_Carbene_Stabilized_Siladiimide/2092270
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资源简介：
The reaction of the N-heterocyclic-carbene-stabilized
disilicon(0) complex [IPr→SiSi←IPr] (1; IPr = :C{N(Ar)CH}2 and Ar = 2,6-iPr2C6H3) with ArN3 afforded
the N-heterocyclic-carbene-stabilized siladiimide [ArNSi(IPr)NAr]
(2). X-ray crystallography and theoretical studies show
that the N–Si–N skeleton in compound 2 possesses
considerable double-bond character and the Si atom is stabilized by
the N-heterocyclic carbene.
创建时间：
2016-02-12
