The First Cobalt Metallacrowns: Preparation and Characterization of Mixed-Valence Cobalt(II/III), Inverse 12-Metallacrown-4 Complexes
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https://figshare.com/articles/dataset/The_First_Cobalt_Metallacrowns_Preparation_and_Characterization_of_Mixed_Valence_Cobalt_II_III_Inverse_12_Metallacrown_4_Complexes/3286234
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资源简介：
Aerobic reactions of Co(O2CMe)2·4H2O with di-2-pyridyl ketone
oxime (Hpko) in the presence of counterions (ClO4-, PF6-) give
the tetranuclear, mixed-valence cobalt(II/III) clusters [CoII2CoIII2(OR)2(O2CMe)2(pko)4S2]X2 [R = H, S = MeOH, X = ClO4
(1); R = Me, S = EtOH, X = PF6 (2)] depending on the solvent
mixture. Complexes 1 and 2 are the first Co members in the family
of metallacrowns adopting the extremely rare inverse 12-metallacrown-4 motif.
创建时间：
2016-05-06
