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Syntheses and Magnetic Properties Study of Isostructural BiM2BP2O10 (M = Co, Ni) Containing a Quasi-1D Linear Chain Structure

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Syntheses_and_Magnetic_Properties_Study_of_Isostructural_BiM_sub_2_sub_BP_sub_2_sub_O_sub_10_sub_M_Co_Ni_Containing_a_Quasi_1D_Linear_Chain_Structure/2494918
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We present here the structures and magnetism of two quasi-1D linear chain compounds of BiM2BP2O10 (M = Co, Ni), which were synthesized by traditional solid-state reactions for the first time. Two title compounds crystallize in the monoclinic system with space group P21/c and feature novel 3D structures with a linear chain structure of {MO6}n further connected by [BP2O10]7– anionic groups. The results of magnetic property measurements evidence the antiferromagnetic properties of both compounds in low magnetic field and a field-dependent metamagnetic transition from the antiferromagnetic to ferromagnetic ground state of the BiCo2BP2O10 complex.
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2016-02-20
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