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A Homochiral Microporous Hydrogen-Bonded Organic Framework for Highly Enantioselective Separation of Secondary Alcohols

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NIAID Data Ecosystem2026-03-08 收录
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A homochiral microporous hydrogen-bonded organic framework (HOF-2) based on a BINOL derivative has been synthesized and structurally characterized to be a uninodal 6-connected {3355667} network. This new HOF exhibits not only a permanent porosity with the BET of 237.6 m2 g–1 but also, more importantly, a highly enantioselective separation of chiral secondary alcohols with ee value up to 92% for 1-phenylethanol.

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2014-01-15
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