Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α‑Diazo-β-ketoesters
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下载链接：
https://figshare.com/articles/dataset/Synthesis_of_Spiro_Ketals_Orthoesters_and_Orthocarbonates_by_CpRu_Catalyzed_Decomposition_of_Diazo_ketoesters/2087542
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资源简介：
Reactions of α-diazo-β-ketoesters
with cyclic ketones,
lactones, and carbonates are reported. Thanks to the combined use
of salt [CpRu(CH3CN)3][BArF] and
1,10-phenanthroline as catalyst for the diazo decomposition, effective
and practical syntheses of spiro bicyclic ketals, orthoesters, and
orthocarbonates are afforded.
创建时间：
2016-02-12
