遇见数据集

Yb(OTf)<sub>3</sub>‑Mediated Access to Furans from β‑Ketothioamides via Eschenmoser Sulfide Contraction Reaction

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NIAID Data Ecosystem2026-03-09 收录
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A mild and straightforward synthetic protocol for construction of a furan skeleton promoted by Yb­(OTf)3 from β-ketothioamides and arylglyoxals has been developed at room temperature. Importantly, this protocol involves a tandem sequence that includes aldol condensation, N-cyclization, ring opening, O-cyclization, S-cyclization, and Eschenmoser sulfide contraction.

创建时间:
2016-02-12
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