Enforced η<sup>1</sup>-Fluorenyl Coordination to Rhodium(I) with the [FluPPh<sub>2</sub>NPh]<sup>-</sup> Ligand
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
The fluorenyl-phosphazene ligand 2 has been prepared and coordinated to the RhI(nbd) fragment. X-ray analyses and DFT calculations substantiate the preference of the re-sulting complex 3 for κ2-N,C over η5-fluorenyl coordination. Despite the associated geometry constraint, the coordination of the short phosphazene sidearm is shown to enforce η1-fluorenyl coordination.
创建时间：
2006-09-25
