In- or In(I)-Employed Diastereoselective Reformatsky-Type Reactions with Ketones: <sup>1</sup>H NMR Investigations on the Active Species
收藏NIAID Data Ecosystem2026-03-06 收录
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An efficient In- or In(I)-based stereoselective C−C bond formation is reported; the diastereoselective Reformatsky-type reactions of ketones. The predominant formations of anti isomers, confirmed by the X-ray structure analyses of ester derivatives of respective alcohols 9a1 and 13a1, conclusively revealed the stereochemistry of the reaction path. 1H NMR investigations revealed the formation of two types of α-metalated transient species from α-halo esters with In or In(I) halides.
创建时间：
2004-11-25
