Synthetic Studies on the MARDi Cascade: Stereoselective Synthesis of Heterocyclic Seven-Membered Rings
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下载链接:
https://figshare.com/articles/dataset/Synthetic_Studies_on_the_MARDi_Cascade_Stereoselective_Synthesis_of_Heterocyclic_Seven_Membered_Rings/3054070
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资源简介:
A versatile stereoselective synthesis of substituted and functionalized heterocyclic seven-membered rings is described. The approach involves
a formal two-carbon ring expansion of heterocyclic cyclopentanones through a base-induced anionic domino three-component transformation
named the MARDi cascade leading either to oxa-, aza-, or thiacycloheptanes bearing up to five contiguous stereogenic centers.
创建时间:
2006-10-12



