Strong Enantioselective Self-Recognition of a Small Chiral Molecule
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https://figshare.com/articles/dataset/Strong_Enantioselective_Self_Recognition_of_a_Small_Chiral_Molecule/3003163
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资源简介：
In the present report, we have crystallized a single enantiomer and the racemate of N-3,5-dinitrobenzoyl (DNB) leucine. In both cases, the
X-ray structures show clear evidence of homochiral dimerization in the solid state. Moreover, only homochiral dimers were observed in the
unit cell of the racemate, a result of solid-state enantioselective complexation. The crystal structures support a chiral recognition mechanism
involving two hydrogen bonds and an offset π−π interaction between the DNB rings.
创建时间：
2016-02-29
