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Pressure-Tuning Interactions in Spin-Crossover Metal-Organic Frameworks

B2FIND2026-04-25 收录

自旋交叉材料

金属有机框架压力调控

数据链接：

https://b2find.eudat.eu/dataset/f1f059ba-e80d-5f0c-b22e-feee7b57d018 数据链接链接失效反馈

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资源简介：

The magnetism of spin-crossover (SCO) materials containing Fe(II) can be switched by changing conditions. The low-spin state existing at low temperature or high pressure can be...

应用场景：

自旋交叉材料

晶体相变

An iron(II) complex with ferrocenyl groups, [Fe(dppFc)2](BF4)2·2Et2O (1·2Et2O, dppFc = 1-ferrocenyl-2-{(2,6-bis(pyrazolyl)pyridyl}ethylene), was prepared. X-ray crystallographic analyses revealed that

NIAID Data Ecosystem110

Influence of Selenocyanate Ligands on the Transition Temperature and Cooperativity of bapbpy-Based Fe(II) Spin-Crossover Compounds

自旋交叉材料

配位化合物结构

Coordination of the ligand bapbpy (1, bapbpy = N,N′-di(pyrid-2-yl)-2,2′-bipyridine-6,6′-diamine), of one of its four dimethyl-substituted analogues 2–5 (R2bapbpy = N,N′-di(methylpyrid-2-yl)-2,2′-bip

NIAID Data Ecosystem50

Enforcing Multifunctionality: A Pressure-Induced Spin-Crossover Photomagnet

自旋交叉材料

高压光磁效应

Photomagnetic compounds are usually achieved by assembling preorganized individual molecules into rationally designed molecular architectures via the bottom-up approach. Here we show that a magnetic r

NIAID Data Ecosystem50

Study on the dynamical spin equilibrium of (n-C2H5)4N[ZnIIFeIII(C2O3S)3] unde...

自旋交叉材料

分子磁学动力学

The main purpose of this proposed experiment is to investigate the time scale of the dynamical spin equilibrium for the iron(III) site in (n-C2H5)4N[ZnIIFeIII(mto)3] (mto =...

B2FIND50

Rhodamine 6G-Labeled Pyridyl Aroylhydrazone Fe(II) Complex Exhibiting Synergetic Spin Crossover and Fluorescence

自旋交叉材料

荧光协同效应

Here, we use a pyridinecarbaldehyde rhodamine 6G hydrazone ligand (L) to synthesize an Fe(II) complex 1 for the search of new fluorescent-spin crossover (SCO) materials. Single-crystal structural det

NIAID Data Ecosystem50

Pressure-Tuning Interactions in Spin-Crossover Metal-Organic Frameworks

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