Silane–Allyl Coupling Reactions of Cp(iPr2MeP)Fe(η3‑C3H5) and Synthetic Access to the Hydrido–Dinitrogen Complex Cp(iPr2MeP)FeH(N2)

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数据链接：

https://figshare.com/articles/dataset/Silane_Allyl_Coupling_Reactions_of_Cp_sup_i_i_i_sup_Pr_sub_2_sub_MeP_Fe_sup_3_sup_C_sub_3_sub_H_sub_5_sub_and_Synthetic_Access_to_the_Hydrido_Dinitrogen_Complex_Cp_sup_i_i_i_sup_Pr_sub_2_sub_MeP_FeH_N_sub_2_sub_/2205901 数据链接链接失效反馈

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资源简介：

Herein we report reactions of the iron allyl complex Cp*(iPr2MeP)Fe(η3-C3H5) with sterically demanding silanes. These reactions lead to stoichiometric hydrosilation of the allyl ligand and dehydrocoupling reactions between the silane and the allyl group. Furthermore, this system has allowed access to a novel Si–H oxidative addition–reductive elimination equilibrium involving Cp*(iPr2MeP)FeH2(SiH2DMP) and Cp*(iPr2MeP)FeH(N2), which was independently synthesized.

创建时间：

2015-06-08

Silane–Allyl Coupling Reactions of Cp*(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)Fe(η<sup>3</sup>‑C<sub>3</sub>H<sub>5</sub>) and Synthetic Access to the Hydrido–Dinitrogen Complex Cp*(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)FeH(N<sub>2</sub>)

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相关数据集

Silane–Allyl Coupling Reactions of Cp(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)Fe(η<sup>3</sup>‑C<sub>3</sub>H<sub>5</sub>) and Synthetic Access to the Hydrido–Dinitrogen Complex Cp(<sup><i>i</i></sup>Pr<sub>2</sub>MeP)FeH(N<sub>2</sub>)