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Novel Double Insertion of Carbon Disulfide into Two Ru−H Bonds of [(dppm)<sub>2</sub>Ru(H)<sub>2</sub>] (dppm = Ph<sub>2</sub>PCH<sub>2</sub>PPh<sub>2</sub>): Synthesis and Crystal Structure of a Methanedithiolate Complex

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NIAID Data Ecosystem2026-03-06 收录
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Addition of excess carbon disulfide to cis/trans-[(dppm)2Ru(H)2] results in the methanedithiolate complex [(dppm)2Ru(η2-S2CH2)] 4 via the intermediacy of cis-[(dppm)2Ru(H)(SC(S)H)] 2. The X-ray crystal structure of this species has been determined.

创建时间:
2016-08-17
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