Catalytic Enantioselective Oxaziridination
收藏NIAID Data Ecosystem2026-03-07 收录
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The first catalytic enantioselective synthesis of oxaziridines is presented. The oxidation of aryl and alkyl aldimines with m-CPBA under organocatalytic conditions using cinchona alkaloid-derived catalysts furnished optically active oxaziridines in good yields and high enantioselectivities (up to 94% ee). Mechanistic investigations indicate a stepwise enantioselective oxidation process.
创建时间：
2011-09-28
