N–O Bond Homolysis of an Iron(II) TEMPO Complex Yields an Iron(III) Oxo Intermediate
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https://figshare.com/articles/dataset/N_O_Bond_Homolysis_of_an_Iron_II_TEMPO_Complex_Yields_an_Iron_III_Oxo_Intermediate/2530090
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资源简介：
The reaction of TEMPO with the iron(I) synthon PhB(MesIm)3Fe(COE) leads to formation of the κ1-TEMPO
complex
PhB(MesIm)3Fe(TEMPO). Structural and spectroscopic data
establish the complex contains divalent iron bound to a nitroxido
anion and is isoelectronic to an iron(II) peroxo complex. Thermolysis
of the complex results in N–O bond homolysis, leading to the
formation of an iron(III) oxo intermediate. The oxo intermediate is
active in oxygen atom transfer reactions and can be trapped by the
triphenylmethyl radical to give the iron(II) alkoxo complex PhB(MesIm)3Fe(OCPh3).
创建时间：
2012-04-18
