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Palladium-Catalyzed Asymmetric Formal [3+2] Cycloaddition of Vinyl Cyclopropanes and β,γ-Unsaturated α‑Keto Esters: An Effective Route to Highly Functionalized Cyclopentanes

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NIAID Data Ecosystem2026-03-07 收录
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https://figshare.com/articles/dataset/Palladium_Catalyzed_Asymmetric_Formal_3_2_Cycloaddition_of_Vinyl_Cyclopropanes_and_Unsaturated_Keto_Esters_An_Effective_Route_to_Highly_Functionalized_Cyclopentanes/2470471
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资源简介:
Palladium-catalyzed asymmetric formal [3+2] cycloaddition of vinyl cyclopropanes and β,γ-unsaturated α-keto esters proceeded smoothly in the presence of chiral imidazoline–phosphine ligands to give the corresponding highly functionalized cyclopentanes in good yields along with high diastereo- and enantioselectivities under mild conditions.
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2012-11-12
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