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Multiferroic Homochiral Metal−Organic Framework

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NIAID Data Ecosystem2026-03-06 收录
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The hydrothermal reaction of (l)-ethyl lactate (Lig-Et) with Tb(ClO4)3·6H2O gives colorless block (Lig)2Tb(H2O)2(ClO4) (1), in which 1 displays a laminar 2D framework. Ferroelectric and magnetic property measurements reveal that 1 probably is the first example of two “ferroic” metal−organic frameworks. Ferroelectricity of its analogue, (Lig)2Tb(D2O)2(ClO4) (2), further confirms the presence of the ferroelectric deuterium effect.

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2008-02-04
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