One-Pot Construction of Aza- or Oxa-Bridged Benzocycloheptanes from Readily Available 2,3-Allenyl Malonates or 2,3-Allenols and o-Iodobenzaldehyde or Imine
收藏Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/One_Pot_Construction_of_Aza_or_Oxa_Bridged_Benzocycloheptanes_from_Readily_Available_2_3_Allenyl_Malonates_or_2_3_Allenols_and_i_o_i_Iodobenzaldehyde_or_Imine/2694526
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资源简介：
A Pd(OAc)2-catalyzed reaction of 2,3-alkadienyl malonates or 2,3-allenols with o-iodobenzaldehyde or its N-tosyl imine occurred smoothly in MeCN at 80 °C to form the oxa- or aza-bridged benzocycloheptane derivatives with important biological potential. With the optically active 2,3-allenols, the absolute configurations of all the three chiral centers have been conveniently established.
创建时间：
2016-02-23
