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Dimeric and Tetrameric Supramolecular Aggregates of Single-Molecule Magnets via Carboxylate Substitution

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Dimeric_and_Tetrameric_Supramolecular_Aggregates_of_Single_Molecule_Magnets_via_Carboxylate_Substitution/2360680
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[Mn3]2 and [Mn3]4 supramolecular aggregates of weakly exchange-coupled MnIII3 single-molecule magnets (SMMs) with S = 6 have been prepared by carboxylate substitution on [Mn3O­(O2CMe)3(mpko)3]+ [mpkoH = methyl­(pyridine-2-yl) ketone oxime)] with the dicarboxylic acids α-truxillic acid and fumaric acid, respectively. The method opens up a new approach to Mn3 SMM aggregates of various size and topology.
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2016-02-18
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