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Synthesis of Hexa(furan-2-yl)benzenes and Their π‑Extended Derivatives

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NIAID Data Ecosystem2026-03-09 收录
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The first synthesis of hexa­(furan-2-yl)­benzene derivatives is described. The RhCl3/i-Pr2NEt-catalyzed cyclotrimerization of di­(furan-2-yl)­acetylenes was an effective method for constructing hexa­(furan-2-yl)­benzene derivatives in good yields. Their π-extended derivatives were also synthesized by Suzuki–Miyaura coupling between hexakis­(5-Bpinfuran-2-yl)­benzene (Bpin = (pinacolato)­boryl) and several aryl iodides.

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2016-02-19
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