Dinitrogen Functionalization Affording Chromium Hydrazido Complex
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https://figshare.com/articles/dataset/Dinitrogen_Functionalization_Affording_Chromium_Hydrazido_Complex/7800416
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资源简介：
A series of trinuclear
and dinuclear Cr(I)–N2 complexes bearing cyclopentadienyl-phosphine
ligands were synthesized
and characterized. Further reduction of the Cr(I)–N2 complexes generated anionic Cr(0)–N2 complexes,
which could react with Me3SiCl to afford the first chromium
hydrazido complex from N2 functionalization. These complexes
were found to be effective catalysts for the transformation of N2 into N(SiMe3)3.
创建时间：
2019-03-04
