Structural Characterization and Dynamic Solution Behavior of the Disodio and Lithio−Sodio Geminal Organodimetallics [{{Ph<sub>2</sub>P(Me<sub>3</sub>Si)N}<sub>2</sub>CNa<sub>2</sub>}<sub>2</sub>] and [{{Ph<sub>2</sub>P(Me<sub>3</sub>Si)N}<sub>2</sub>CLiNa}<sub>2</sub>]
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数据链接：
https://figshare.com/articles/dataset/Structural_Characterization_and_Dynamic_Solution_Behavior_of_the_Disodio_and_Lithio_Sodio_Geminal_Organodimetallics_Ph_sub_2_sub_P_Me_sub_3_sub_Si_N_sub_2_sub_CNa_sub_2_sub_sub_2_sub_and_Ph_sub_2_sub_P_Me_sub_3_sub_Si_N_sub_2_sub_CLiNa_sub_2_sub_/3065500数据链接链接失效反馈
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资源简介：
The title disodio complex may be prepared by the double deprotonation of a neutral bis(phosphinimine) ligand using 2 equiv of the strong base n-BuNa, whereas the mixed Li/Na derivative can be prepared by controlled sequential deprotonation, by transmetalation, or by mixing the homometallic analogues. The compounds form dimers with the ligands capping an Na4 square or a Li2Na2 rhomboid, and these are the first examples of R2C2- dianions containing a heavy alkali metal to be structurally characterized.
创建时间：
2006-08-14
