Electron-Poor Pentafluorophenyl-Substituted PCP−Palladium Pincer Complexes
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https://figshare.com/articles/dataset/Electron_Poor_Pentafluorophenyl_Substituted_PCP_Palladium_Pincer_Complexes/3289852
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资源简介:
A novel fluoroaryl-substituted PCP ligand
has been synthesized and used to generate the corresponding Pd complexes. The bonding of the fluoroaryl
phosphine has been investigated by X-ray crystallography, NMR spectroscopy, and a competition experiment,
which indicate that the ligand is sterically comparable
to its well-known phenyl analogue but clearly imparts
significant electronic differences to the metal center.
创建时间:
2016-05-06



