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Electron-Poor Pentafluorophenyl-Substituted PCP−Palladium Pincer Complexes

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Electron_Poor_Pentafluorophenyl_Substituted_PCP_Palladium_Pincer_Complexes/3289852
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A novel fluoroaryl-substituted PCP ligand has been synthesized and used to generate the corresponding Pd complexes. The bonding of the fluoroaryl phosphine has been investigated by X-ray crystallography, NMR spectroscopy, and a competition experiment, which indicate that the ligand is sterically comparable to its well-known phenyl analogue but clearly imparts significant electronic differences to the metal center.
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2016-05-06
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