Corannulene Subunit Acts as a Diene in a Cycloaddition Reaction: Synthesis of C<sub>80</sub>H<sub>32</sub> Corannulyne Tetramer
收藏NIAID Data Ecosystem2026-03-07 收录
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资源简介：
Distortion of six-membered rings in corannulene subunits of corannulyne (1,2-didehydrocorannulene) cyclotrimer activates the system for a cycloaddition reaction with another corannulyne unit. This unprecedented cycloaddition in which a corannulene fragment acts as a diene produces the largest oligomer of corannulyne reported to date. X-ray crystallography reveals the highly nonplanar structure of the tetramer which exhibits conformational and optical absorption properties very different from those of the cyclotrimer.
创建时间：
2012-09-21
