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Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives

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https://figshare.com/articles/dataset/Palladium_III_Catalyzed_Fluorination_of_Arylboronic_Acid_Derivatives/2373310
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资源简介:
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd­(III) intermediate that has been isolated and characterized.
创建时间:
2016-02-18
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