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Rh(III)-Catalyzed Selective Coupling of N‑Methoxy‑1H‑indole-1-carboxamides and Aryl Boronic Acids

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Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Rh_III_Catalyzed_Selective_Coupling_of_i_N_i_Methoxy_1_i_H_i_indole_1_carboxamides_and_Aryl_Boronic_Acids/2277892
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A Rh­(III)-catalyzed selective coupling of N-methoxy-1H-indole-1-carboxamide and aryl boronic acids is reported. The coupling is mild and efficient toward diverse product formation, with selective C–C and C–C/C–N bond formation. Kinetic isotope effects studies were conducted to reveal a mechanism of C–H activation and electrophilic addition.
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2016-02-17
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