Structure and Reactivity of Ag(I) Complexes Bearing Tridentate Phosphinine Ligands
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https://figshare.com/articles/dataset/Structure_and_Reactivity_of_Ag_I_Complexes_Bearing_Tridentate_Phosphinine_Ligands/22770835
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资源简介：
Structure and reactivity of novel
Ag(I) complexes with tridentate
phosphinine (phosphabenzene) ligands are discussed in this article.
An equilibrium between the dimer and the monomer was observed for
the λ3-phosphinine Ag(I) complex in the solution
state. The λ3-phosphinine Ag(I) complex can be oxidized
by PhI(OAc)2 to afford λ5-phosphinine
species, maintaining the coordination to the metal center. Photochemical
properties of the Ag(I) complexes were also investigated, and the
emission of the λ3-phosphinine Ag(I) complex showed
solvatochromic behavior.
创建时间：
2023-05-05
