Ru4(CO)8(μ-OOCAd)4(PPh3)2: Phosphine Derivative of an Electron-Deficient Linear Tetraruthenium Cluster
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The reaction of Ru3(CO)12 with 1-adamantanecarboxylic acid afforded a purple solid with the formulation Ru2(CO)4(μ-OOCAd)2 (Ad = 1-adamantyl). Reaction of this solid with PPh3 gave Ru4(CO)8(μ-OOCAd)4(PPh3)2, a 64-electron linear tetraruthenium cluster.
创建时间：
2016-02-22
