Synthesis and Characterization of the Dodecahexaynediyldiiron Complex, Fp*−(C⋮C)<sub>6</sub>−Fp* [Fp*= Fe(η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)(CO)<sub>2</sub>], the Longest Structurally Characterized Polyynediyl Complex
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Cu-catalyzed oxidative coupling of the hexatriynyl complex Fp*−(C⋮C)3−H affords the dodecahexynediyl diiron complex Fp*−(C⋮C)6−Fp*. Its linear but slightly twisted structure has been revealed by X-ray crystallography.
创建时间：
2016-08-27
