[Cu(L)Mn(N<sub>3</sub>)<sub>2</sub>]<i><sub>n</sub></i>: The First Complex Containing Both Macrocyclic Oxamido and Alternate (μ-1,1 and μ-1,3) Azido Bridges
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A wattle-type heteropolynuclear complex [(CuL)Mn(N3)2]n (1) (H2L = 2,3-dioxo-5,6:15,16-dibenzo-1,4,8,13-tetraazacyclo-pentadeca-7,13-diene), which represents the first system with macrocyclic oxamido and alternate azido bridges, forming a one-dimensional chain structure, has been synthesized and characterized by a low temperature magnetic study. The chains are stacked with interchain hydrogen and lead to the structure of a three-dimensional network.
创建时间:
2016-10-12



