Investigation of the photoactivation mechanism of Fe3(CO)12 using time-resolv...

B2FIND2026-04-25 收录

有机金属光化学

时间分辨光谱

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Trimetallic carbonyl clusters (M3(CO)12) containing group 8 elements such as iron, ruthenium and osmium are historic molecules in the field of organometallic photochemistry and...

Ring-Opening Reaction of Phosphorus-Bridged [1]Ferrocenophane via Ring Slippage from η 5 - to η-Cp

有机金属光化学

二茂铁衍生物

A reaction mechanism was investigated for a ring-opening reaction of RP(E)-bridged [1]ferrocenophane, where RP(E) = PhP(S) (3a), PhP (3b), and MesP (3c) (Mes = 2,4,6-trimethylphenyl). Irradiation of U

NIAID Data Ecosystem90

Controlling the Minimal Self Assembly of “Complex” Polyoxometalate Clusters

多金属氧酸盐

时间分辨光谱

Despite the vast number of polyoxometalate clusters now known, an ongoing and important challenge is to understand causality in the assembly of “complex” clusters at a mechanistic level, since this is

NIAID Data Ecosystem40

Photochemical cis − trans Isomerization of cis -(η 6 -1,2-Diphenylethene)Cr(CO) 3 and the Molecular Structure of trans -(η 6 -1,2-Diphenylethene)Cr(CO) 3

有机金属光化学

光致异构化反应

Visible irradiation of cis-(η6-1,2-diphenylethene)Cr(CO)3 results in an efficient conversion to the trans isomer as confirmed by NMR, room-temperature UV−vis spectroscopy, and low-temperature matrix i

NIAID Data Ecosystem30

Photo-Induced Reaction of Cp*Ru(μ-H)4RuCp* with Arenes Resulting in Irreversible Formation of μ‑η2:η2‑Cyclohexadiene Complexes

有机金属光化学

芳烃去芳构化反应

In contrast to the thermal reaction of [Cp*Ru(μ-H)4RuCp*] (1: Cp* = η5-C5Me5) with benzene at 70 °C yielding an equilibrium mixture of 1 and [{Cp*Ru(μ-H)}2(μ-η2:η2-C6H8)] (2), the UV irradiation of 1

Figshare2022-11-11 更新40

Investigation of C–C Bond Activation of sp–sp2 C–C Bonds of Acetylene Derivatives via Photolysis of Pt Complexes

有机金属光化学

碳碳键活化

Carbon–carbon bond activation reactions of acetylene derivatives featuring sp–sp3 C–C bonds or both sp–sp2 and sp–sp single C–C bonds were studied via photolysis of platinum compounds. Novel Pt0–acety

Figshare2016-02-13 更新40

Investigation of the photoactivation mechanism of Fe3(CO)12 using time-resolv...

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