Synthesis and Structural Characterization of a Nonplanar Neutral [36]Metallacrown-12 Nickel Compound [Ni(C<sub>13</sub>H<sub>9</sub>N<sub>3</sub>O<sub>2</sub>)(CH<sub>3</sub>OH)]<sub>12</sub>
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A nonplanar metallacrown [Ni−N−N]12 was achieved using a pentadente ligand, salicylaldehyde 2-pyridinecarboxylhydrazone (H2L) via a new modular self-assembly approach. The special bridging models of the ligand forced the macrocycle to form in a specific size with the wavelike conformation.
创建时间：
2016-05-05
