Gas-Phase Investigations on the Transmetalation Step in Sonogashira Reactions
收藏NIAID Data Ecosystem2026-03-08 收录
数据链接：
官方服务：
资源简介：
The microscopic reverse of the transmetalation step in the Pd/M (M = Cu, Ag, Au) catalyzed Sonogashira-type reactions has been observed in the gas phase upon collision-induced dissociation (CID) of the heterobimetallic complexes. Measuring the activation energies by quantitative energy-resolved CID experiments provides an upper bound for the internal rearrangement energies. The potential-energy surface is investigated by density functional theory calculations and compared to the experimental values.
创建时间：
2016-02-13
