Total Synthesis of (+)-Iresin
收藏Figshare2016-02-13 更新2026-04-29 收录
下载链接：
https://figshare.com/articles/dataset/Total_Synthesis_of_Iresin/2166355
下载链接
链接失效反馈官方服务：
资源简介：
The first asymmetric total synthesis of (+)-iresin (4), an historically important ent-Drimane sesquiterpene lactone, was realized from aldehyde 3 via cyclic orthoester 6 in 5 steps. Notable transformations in this synthesis include a tandem trifluoroperacetic acid (TFPAA)-mediated Baeyer–Villiger oxidation–olefin epoxidation–epoxy ester cyclization, regioselective Burgess dehydration, and regioselective Fétizon oxidative lactonization.
创建时间：
2016-02-13
