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Intramolecular Diels−Alder Cycloadditions of Fulvenes. Application to the Kigelinol, Neoamphilectane, and Kempane Skeletons

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NIAID Data Ecosystem2026-03-06 收录
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A variety of polycyclic ring skeletons (e.g., kigelinol, neoamphilectane, and kempene systems) can be prepared rapidly via intramolecular Diels−Alder cycloadditions (IMDA) of fulvenes. The length of the tethers and the diversity of the substituents on the fulvene core dictate the nature of the IMDA pathway.

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2016-05-06
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