Highly Efficient and Regioselective Allylation with Allylic Alcohols Catalyzed by [Mo<sub>3</sub>S<sub>4</sub>Pd(η<sup>3</sup>-allyl)] Clusters
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
A highly efficient and regioselective allylation reaction of amines and active methylene compounds directly using allylic alcohols under mild conditions catalyzed by the novel cubane-type sulfido [(Cp*Mo)3(μ3-S)4Pd(η3-allyl)][PF6]2 clusters has been developed. A variety of allylic alcohols and nucleophiles including amines and active methylene compounds are investigated, and in the case of allylic alcohols bearing substituents at either the α- or γ-position only linear products are obtained.
创建时间：
2016-02-24
