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Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes

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https://figshare.com/articles/dataset/Gold_I_Catalyzed_Enantioselective_4_2_Cycloaddition_of_Allene_dienes/2803366
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资源简介:
An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C3-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively.
创建时间:
2010-01-01
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