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Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes

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NIAID Data Ecosystem2026-03-06 收录
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An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C3-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively.

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2010-01-01
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