Exploring the Assembly of Supramolecular Polyoxometalate Triangular Morphologies with Johnson Solid Cores: [(MnII(H2O)3)2(K⊂{α-GeW10MnII2O38}3)]19–
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资源简介：
A new polyoxometalate (POM) cluster compound is presented which incorporates a trimeric assembly of Keggin-type germanotungstate fragments trapping a Johnson-type solid {Mn8} core. The mixed K–Li salt of the polyanion [(MnII(H2O)3)2(K⊂{α-GeW10MnII2O38}3)]19– was characterized in the solid state and solution. The correlation of the assembly processes and the observed architecture of the “trinity” family of POMs is discussed.
创建时间：
2016-02-22
